Organic Reactions Scheme Analysis
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1. (a) What is an unsaturated hydrocarbon compound (1mk)
(b) The scheme below shows a series of reactions starting with propanol. Study it and answer the questions that follow.
(i) Name the type of reaction in step I and II (2mks)
(ii) Write the equation for the reaction that takes place in Step III (1mks)
(i) Name the substance labelled A, C, D and E. (2mks)
(ii) Draw the structural formula of product C (1mk)
(iii) Name the process in step (IV) (1mk)
(iv) Name compound B and state the type of reaction involved in its formation. (2mks)
(v) If the relative molecular mass of B is 35,700 determine the value of n. (2mks)
This question includes visual content: A flowchart showing chemical reactions. Propanol reacts via Step I (H+/KMnO4) to propanoic acid ($CH_3CH_2COOH$), which then reacts with potassium to produce 'Solution A + Hydrogen gas' and with propanol/butanol to form an ester, or with sodium to form $CH_3CH_2COONa$. $CH_3CH_2COONa$ leads to $CH_3CH_3$ (ethane) in Step 3, which then forms 'Compound D + HCl'. Separately, propanol reacts via Step II to $CH_2=CHCH_3$ (propene), which reacts with HCl to form 'Compound E' and with $Cl_2$ (implied polymerization) to form 'Compound B'. Step IV shows the reaction of propanoic acid with butanol in the presence of conc. $H_2SO_4$ to produce 'Product C + H2O'.
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Hi Jackline, let’s explore this organic chemistry reaction scheme starting with propanol and identify each compound and process.
Organic Chemistry Reaction Scheme Analysis
In step one, propanol reacts with acidified potassium manganate seven. Since this reagent is a strong oxidizing agent, propanol is oxidized to propanoic acid. Thus, step one is an oxidation reaction.
Part (b)(i): Reaction Types
In step two, propanol is converted to propene. Since we are removing water from an alcohol to form an alkene, this is a dehydration reaction.
Now let's identify the substances. Substance A is formed when propanoic acid reacts with potassium metal. This is a reaction between an acid and a metal, producing a salt and hydrogen gas. Therefore, A is potassium propanoate.
Part (b)(i): Identifying Substances
Product C is formed in step four by the reaction of propanoic acid and butanol in the presence of concentrated sulfuric acid and heat. This is an esterification process, and C is the ester butyl propanoate.
Compound E is formed by adding hydrogen chloride to propene. According to Markovnikov's rule, the chlorine adds to the second carbon, giving us two-chloropropane.
Finally, compound D is formed from ethane reacting with chlorine gas. This is a substitution reaction producing chloroethane and hydrogen chloride.
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